生物学(一)1试题)
南阳一中2023届高三第三次阶段性测试生物答案1-5 BACAB6-10 BDCCD11-15 CCDAD16-20 CDCBC21-25 BCBCC26-30 CBDCB31-35 DBDCD36-40 CBBDB41.（每空1分，共8分)(I)细胞膜及细胞内：D(2)神经递质、甲状腺激素（答全给分）(3)乙：偏高(4)0.8-12gL:神经：葡萄糖、神经递质、胰高血糖素（答全给分）42.（每空1分，共7分)(1)对传入的信息进行分析和综合(2)有：无(3)收缩：不属于(4)兴奋或抑制(5)B43.（每空1分，共9分)(I)下丘脑；TRH是下丘脑分泌的，当注射适量的TRH后，垂体分泌的TSH水恢复至接近正常，表明垂体是正常的。(2)垂体(3)基础（初始）TRH分泌量：适量甲状腺素：等量TSH(必须答出“等量”)仅是甲组TRH分泌量明显减少：仅是乙组TH分泌量明显减少：甲、乙组TRH分泌量均明显减少44.（每空2分，共10分)()去甲肾上腺素为神经递质，可直接通过突触结构控制松果体(2)远离手机，合理作息：闭灯睡觉：必要时可以服用含有褪黑素的药物，但是切勿长时间服用，服用剂量遵医嘱(3)不能；不能排除下丘脑和垂体对睾丸分泌的影响(4)抑制肿瘤细胞的增殖，诱导肿瘤细胞的凋亡45.(每空1分，共6分)(1)免疫系统的第一道防线被破坏，防卫功能减弱（或黏膜受损会导致病毒直接突破第一道防线)(2)胸腺(3)淋巴因子和抗原（答全得分）沉淀(4)防卫(5)再次接触VZV,机体内的记忆细胞迅速增殖分化形成浆细胞，快速产生大量的抗体，能在短时间使大多数病毒被灭活，所以症状较轻
(3)二、非选择题：本题共5小题，共60分。21.(11分)聚乙二醇(PEG)作为渗透调节剂，可用于手旱胁迫实验。选取长势一致的山农27号、中麦875两个小麦品种的幼声作为实验材料，利用PEG模拟干早胁迫，下表所示为不同浓度的PEG处理对小麦幼苗光合作用湘应参数的影响。回答下列问题：PEG浓度/蒸腾速率气孔导度/净光合速率(g·L1)(mmol.m2·s-1)(mmol·m2.s-1)(mmol·m2.s1)山农27号中麦875山农27号中麦875山农27号中麦87524.(11迷错误044.042.4629816826.516.8其502.591.142219317.79.8问1000.640.5936418.76.41500.330.5420337.04.8注：气孔导度表示的是气孔张开的程度。(1)小麦叶肉细胞中的叶绿素吸收光能转化到中，供暗反应利用；暗反应的发生场(1新坦牛耳所是v(2)根据表中给出的数据可知，在一定浓度范围内，随着PEG浓度的增大，小麦净光合速率会出现这种变化的原因是(3)对抗干旱胁迫环境反应机制更强的是25.(0(填“山农27号”或“中麦875”)，判断的依据是22.(13分)细胞的分裂与分化、衰老与调亡是生物界的普遍规律和现象。细胞的分裂与分化是生物体生长发育的基础；衰老与调亡有利于细胞的自然更新，维持内部环境的稳定。回答下列有关问题：(1)细胞增殖具有性，细胞增殖包括两个连续过程。细胞通过有丝分裂增殖的意义是养条件(2)同一个人的神经细胞和表皮细胞在形态、结构和功能方面都具有较大差异，出现这些差2)转至异的根本原因是同一个人的神经细胞和表皮细胞中都(填“是”或“否”)。理由是下图所具有控制细胞程序性死亡的基因吗？(3)老年人的头发会变白，这是由于其毛囊中的黑色素细胞衰老，细胞中的降低，黑色素合成减少。在成熟的生物体内，衰老细胞以及某些被病原体感染的细胞的清除，都是通过完成的。23.(13分)苹果的果形有圆形、椭圆形和扁圆形，由两对独立遗传的基因(B、b和D,d控制。以④⑤两个不同基因型的圆形苹果品种作亲本杂交，全部是椭圆形苹果，F:自交，F,苹果中出现椭圆形：圆形：扁圆形=9：6：1的性状分离此。回答下列问题：P:BDP八bD入(1)亲代苹果的基因型是(2)F2中杂合圆形苹果杂交后代表型及比例为430A·【高一生物第5页（共6页）】·23-430A·
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/化学(1-7)答案)
干燥紫色棉线氢氧化钠溶液石营纸花CO-湿润紫色一皮石蕊纸花CO塑料瓶水去顶部的塑料瓶图1图2(2)图1中，塑料瓶内观察到干燥紫色石蕊纸花不变红，湿润紫色石蕊纸花变红，可以说明二氧化碳与水反应。观察到短蜡烛熄灭后，关闭K,片刻后长蜡烛熄灭，由此得到的结论是(3)欲证明CO,能与氢氧化钠溶液发生反应，兴趣小组利用图2所示的装置进行探究实验（实验装置中的夹持仪器已略去）。先挤压胶头滴管，将氢氧化钠溶液滴人充满CO的试管中，再打开止水夹，可以观察到烧杯中的水发生倒吸。①兴趣小组的一些同学得出二者能发生反应的结论，发生反应的化学方程式为,但部分同学认为上述实验不足以证明CO2与氢氧化钠溶液发生了反应，理由是②为进一步证明CO2与氢氧化钠溶液发生了反应，下列实验设计不可行的是(填字母)。A.利用原装置，将氢氧化钠溶液换成水做对比实验，观察现象B.在原实验进行后的试管中继续滴加BaCl2溶液，观察现象C.在原实验进行后的试管中继续滴加酚酞溶液，观察现象【拓展延伸】注意：若答对第(4)小题奖励3分，化学总得分不超过40分。(4)兴趣小组的同学查阅资料后，得到以下信息：20℃时，氢氧化钠、碳酸钠在水、乙醇中的溶解度如下表所示。溶质氢氧化钠碳酸钠溶剂溶解度/g水10921.8乙醇17.3<0.01初中学业水考试最后一卷·化学（二）第7页，共8贞扫描全能王创建
oducing intir suply chin.Theron.Thet uhyce实物摸型.”What can yoo intheearparagrahA.Open nongB.Design3DdigitaldothesforyoursEC.Buya bgger wardrobe for yourbedroom.D.Wearmade byy3.What wen fom Simon'wordn3A.AR technologywill bring achallengeB.One's character will be seen in the virtua ord.C.Digital othes will be more cnefoeoeD.One's expression only can be seen in the physical world.34.What is Simon's attitude to digital clothing?A.Approving.B.Doubtful.C.UnclearD.Grateful.35.What is the text mainly about?A.The increase in AR glasses.B.The digital fashion in the future.C.The virtual body in digital clothes.D.AR glasses made by new technology.第二节（共5小题；每小题2分，满分10分）根据短文内容，从短文后的选项中选出能填入空白处的最佳选项。选项中有两项为多余guins and large areas covered with snow.Large amounts of white snow spreading over thou-选项。When we think of Antarctica,the first thing that comes to our mind is a picture of pen-sands of kilometers is a pretty good description of Antarctica.36Research and observations conducted over the past few years have led to the conclusionthat the Antarctic Peninsula's snow is turning green.These algae even thoughthey are individually incapable of being sen by eyeseisbe omspe.Thesepduce colonies called algal blooms,which spread over large areas.3DAsaresult,Antarctica is visible as many phesof greenan whitesnow om space Alge becaus of therhorophepsnho光合作用.NotuebeeAntarctica leaving the no加0ceoear that suc profondferemains visible in the layers below.ououso Puspun oS1S!UODU=sunlight.∂roundingrea fasterrae meling more o day by dyB.But that legendarysnowis completey whtmrCSometimes eynthe of theA.This is due to algal growth.Dhtaco方eh22-03-383C·【高三英语第6页（共8页）】
二，非选经题：共4夏，共1分4。(15分)薄(T)在左金、半导体等工业中应月广泛，是离精发不发影的分端材科(1)C们可用于制作通厚电地的自极材想。①1形位于元素到系表第5周期，与0元素月荒基海原子给做色子布式为▲②C:的晶跑如竟14玉1所示，与一个Cd原子等委且最近的：原子有▲_个。请在题14密1中面它该是影婚z细方向的面粉彩系盖04题14玉-1题14委2(2)工业上可还原T0国体制名1①响T0:置体中血入HS0:整液、S0,落液，加艺可得Te,反应的化学方程式为▲②反应过程中，反应温度、反应时间时1：的产形响虹题14图3、14墨4所示，工业上一数采致的温度和反应时间为人，选泽该温度的原因是▲是14图时题144@反应过程中，随HSO通多，TE的产率纸，可能的原因是A15。(14分)其核誉为“现代金属”有“战全属”·工业上以其铁主要成分为偏爸酸亚铁FeTO),含Fe、S.AN的氧化物等杂质]制各T0,和O,工艺流症如图。过量好苍水一落血一应一应被面复水说缸复水立与已知：25C时，KF0H1x10,K=Fe0H时x105,KA0H1x10当溶液中离子冻度小于10X10=L1时，认方流流完全：“水解”时反立为0+20一出0，+2H:回答下列同题：(1)制各T0,①“酸没”时m元套转北为T0°，Fe0:发=反应的高子方式为人一·②“酸爱”过程中，在不同温度下下元素的浸出幸交化情况意15图所示.三宽超过C时，浸出率下亮的原因是▲一：题5图高二化学第4页共6页
2024届云南三校高考备考实用性联考卷（一)化学参考答案一、选择题：本题共20小题，第1~10题，每小题2分；第11~20题，每小题3分，共50分。在每小题给出的四个选项中，只有一项是符合题目要求的。题号1234568910答案BCCBDDABDB题号11121314151617181920答案ADBBA【解析】1.丝绸的主要成分是蛋白质，A说法正确。包装食品的塑料袋为聚乙烯，B说法错误。氮化硼陶瓷属于无机非金属材料，C说法正确。“空气捕捉”法能实现从空气中捕获二氧化碳，减少二氧化碳排放，有利于“碳达峰、碳中和”，D说法正确。答案为B。2.⑧02是8号元素，质子数为8，核外电子数为10，其结构示意图为A错误。基态Fe原子的核外电子排布式为[Ar]3d4s2,Fe2+的价层电子排布式为3d6,则Fe2+的价层电子排布图为B错误。银氨络离子中中心离子为银离子，氨3d分子为配体，用箭头表示银氨络离子的配位键为[HN→Ag←-NH]+,C正确。SO3无孤电子对，价层电子对数为3，VSEPR模型是面三角形，与图不相符，D错误。答案选C。3.氨气与水发生可逆反应生成NH3·H2O,且NH3·H2O为弱电解质，部分电离，则在标准状况下，2.24LNH通入水中制成氨水，溶液中NH数目小于0.1NA,A正确。分子式为C2H4O的稳定化合物的结构简式为CH3CHO,分子中含有4个碳氢键，则44gCH:CHO分子中含有碳氢键的数目为，44g,x4 XNAmol=4Wa,B正确。每个环氧乙烷44g/mol分子含有7个共价键，所以0.1mol环氧乙烷（八）共有0.7Na个共价键，C错误。氢
upcoming adventure.words2017.Robn b plane toDarSalam,Tnzanin.The joureysarted withcheckh hero the new cture.She then mde the moveher homeinnycodwith the you participantsEQWIPHUBMShee rutheriubGrls/Boy Club.nviromentClubd glishbnustiaboutrkingith theonthe GrCichedingthe oal n believe that they'rebto becmedive membe theeThat experiene has filled me with more motivation to continue my work towards equality.Itookrrom the countryand the people than I could have ver imagined.'stlin touwithyoftheio I made there,and Im positivelEast Africaa Robin.5.Wh wekow about Robin acording to paragraph 1?A.She is a very experienced volunteer.B.She knew EQWIP HUBs quite well.C.She had volunteered both at home and abroad.D.She enjoys working with any volunteer organization.6.HowdoQWIP HUBs degide the right positions for itsoerAB即ev做hgtheir perfor然ce in the ining.B.By offe哭them a丹ths-long ti22encehu)·C.By conducting several rounds of interviews with them.D.By estimating their level of interest in vouteering.7.The Girls Club intends to help womanA.stay connected with locals经B.remain competitive at workC.become financially independentD.become confident of themselves8.What can we infer from Robin's words?A.She's benefited a lot from the experience.B.The experience is within her expectation.C.Equality at work needs improving in Africa.D.She is more motivated to work in East Africa.Passage 3◇Throughout the world,parents talk more differently to babies than they do to adults.With their入little kids,parents use baby talk,which usually comes with long pauses and pitch()changes.tWhile parents may feel a bit silly using baby talk,they shouldn't.Babies not only prefer listeningto the talk,but they also learn new words more easily from it.By stressing the structure of speech,such as the differences between the vowels"aand,baby talk helps babies translate the sound intomeaningful units of language.Actually,the timbre(plays a roe.The timbre of an instrument clearly affects how we猓理xprnce music,but its oe in language is less obvious.Looking into the timbre of baby tak,wemade mrisng discovere Mothers change their timbre when speaking to babies,as if theyechngr voeifferent irumettotalkto theseister【高考专题突破卷·英语（二）第3页（共6页）】
business'”和第9题解析可知，Burchill在旅店打包。故选D。7.A动词词义辨析。visit参观，拜访；help帮助；follow跟随，遵守；make制作。由空后的“some friends in the area'”可知，此处指“拜访”朋友。故选A。8.C动词词义辨析。sell售卖；have拥有；bring带来；taste品尝。由空后的“some pepperonifrom back east'”可知，此处指他的朋友要求带一些辣肠来。故选C。9.A动词词义辩析。filled装满；locked锁上；紧闭；abandoned抛弃；lost丢失。结合上一题獬析可知，既然朋友要求带辣肠，Burchill把行李箱“装”满了。故选A。lO.D形容词词义辨析。surprised惊讶的；pleased高兴的；excited激动的；worried忧虑的。由空后的“it would be too warmi”可知，Burchill担忧天太热对辣肠有影响。故选D.ll.D动词词义辨析。dug挖；cleared清除；cut切；laid放。由空后out可知此处指摆开，即lay out。故选D。l2.B形容词词义辩析。delicious美味的；safe安全的；soft柔软的；ready准备好。从下文的“and pepperoni-一everywhere'”可推知，此处指Burchill原以为辣香肠是“安全的”。故选B。l3.A动词词义辨析。left落下，离开；nodded点头；waited等候；regretted后悔。从下文的“and opening the door to my room”可知此处指“离开”。故选A。l4.C形容词词义辨析。far远的；funny搞笑的；wrong错误的；blind盲的。结合下文可知此处指事情并不是他原先想的那样。go wrong意为“出毛病，弄错”。故选C。l5.C名词词义辨析。beach沙滩；driveway私人车道，hall过道，走廊；大厅；table桌子。由空后的“and opening the door'”可知此处指他走过走廊。故选C。l6.B名词词义辨析。application应用，申请；apology道歉；request请求；需要；invitation邀请。从下文的“and I admit responsibility for my..”可知此处指道歉。故选B。l7.D形容词词义辨析。hungry饥饿的；dead死亡的；missing迷失的；wild狂野的。从下一句“They rushed to the window...”可知，此处指海鸥被开门声惊吓“发疯”般地冲向窗户。go wild意为“发狂”，为固定词组。故选D。l8.B动词词组词义辨析。wake up醒来；get out离开，出去；take off起飞，脱下；break in打断，闯入。结合上一题解析可知，此处指30或40只海鸥同时从窗边“出去”。故选B。l9.A名词词义辨析。mess混乱；puzzle谜；fight打架，斗争；challenge挑战。由空前的“pepperoni-everywhere.The curtains were falling down,the lamps were falling down"知，辣香肠无处不在。窗帘和灯都掉下来了，因此房间内“一片狼藉”。故选A。2O.D动词词义辨析。recovered恢复；retired退休；escaped逃离；matured成熟。根据上文的“Older and wiser now”可知此处指自己变得“成熟了”。故选D。2l.D名词词义辨析。suffering痛苦，折磨；plans计划；madness疯狂；actions行动，动作。根据空前的“I admit responsibility”可知此处指“行为”。故选D。22.C短语词义辨析。hands in pockets两手抄兜；nose in the air目巾无人；hat in hand毕恭毕敬地；feet on the ground脚踏实地。由空前的“I come to you”和空后的“to apologizefor the damage”可知此处指虔诚地道歉。故选C。23.A副词词义辨析。indirectly间接地；deliberately故意地；cautiously谨慎地；secretly秘密S2·考点纠错卷·英语（1~12)答案第5页（共48页）
will hold aIf you are not a Chinese citizen but want to pursue your postgraduate studres at thUniversity of Saskatchewan,you can choose this scholarship.Their Phd scholarships areUniversity of Saskatchewan Graduate Scholarshipvalued at CA $20.000 each:alternatively.their Master's thesis (is valued atCanada-ASEAN Scholarships and Educational Exchange for Development(SEED)CA$16.000.Deadline to apply is February 22.2022.oengage in a short-term exchange opportunity for study orCanadian post-secondary (institutions at the college,undergraduate and graduatelevels,this scholarship is for you.Do note that only Canadian institutions can submitapplications on behalf of candidates.If you are interested in this scholarship program,contactyour institution to make your interest known and to request information about the application2621.When should you apply for the UdeM International Student Scholarship Programme?process.Deadline is March 4,2022.A.Before February 10th,2022.B.Before March 4th,2022.C.Before March 1st,2022.D.Before February 22nd,2022.22.Which scholarship programme is only available to Chinese citizens?A.Canada-ASEAN Scholarships and Educational Exchange for Development.B.University of Saskatchewan Graduate Scholarship.C.UdeM International Student Scholarship Program.D.CSC-USask Joint Funding Programme.23.What can we learn about the feature of the SEED scholarship program?A.Applications can only be submitted by Canadian institutions.B.Each successful applicant can get CA $16,000 from it.C.There is an age limit for the applicants.D.Students of any level can apply for it.I was a newcomer in a class.So was Alice.That's where the similarities ended.I was talland she was small.My thick,black hair had been recently cut short.Her natural blonde hairflowed to her waist and looked great.I was awkward and shy.She wasn't.I couldn't standher.I considered her my enemy.She liked me.She wanted to be my friend.One day,she invited me over and I said yes-I was too shocked to answer any other way.No one had invited me over to play.But this girl who wore the latest fashions wanted me to goto her home with her after school.I got very surprised when she led me into an apartmentbuilding.She lived on the fourth floor in a two-room place with her mother,her stepfather,her two brothers and her sister.When we got to the room she shared with her sister,she tookout a big caseof Barbieswhich was my next surprise.I would have thought she'd grown toomurerthem.I had ever played with them.But we sat on the foor of a walk-in closet,gnmade upresabout the Barbies.That's when we found out that webodtobe writerswhen we were oder and we both had wild imaginations.We had agreat day that afternoon.Our jaws ached from smiling so much.Shed me her wardrobe,which had mosty come om a designer clothing(rth bokThewo whoitued her aa modesmeimes orhernewspaper ads and gave her clothes in exchange.dtheo hrmed.boktoreee her ashionmagazines,the movie theater gave her free passes and the pizza place let her have free slices.Son I was incuded in her magic world.We sleptoverat each other'shouses,and spent everyreemomen oether.Mydark hairged tolovbeingtl【2022年冲刺押题卷（六）·英语第3页（共8页）】
32.What can be implied about the nitrogen fertilizer according to Paragraph 1?CA.It loses preference of smaltholder farmers due to poor quality.DB.It does no harm to the environment.FGC.It is gained directly from the land.33.What is the natural order of legume plants producing nitrogen fertilizer?D.It is universally used to help crops grow.a.The formation of nodules.b.The bacteria's stability of nitrogen.c.The root's being colonized by the bacteria.d.The provision of sugar to sustain the bacteriae.The interaction of the ro of lumes with soi bacteria.D.daecb4.What does the deried word pilotingmosarlymean?A.abecdB.ecadbC.ceadbD.erasing35.What attitude does theauthorotothe natural nitroen production?A.persuading B.trickingC.guidingA.Optimistic.B.Doubtful.C.Disapproved.D.Unconcerned阅读下面短文，从短文后的选项中选出可以填入空白处的最佳选项。选项中有两项为多余第二节（共5小题；每小题2.5分，满分12.5分）选项炎德文化The ability to communicate is the primary factor that distinguishes human beings fromanimals.36 Good communieation skills are what will make them a happy and successfulsocial being.In order to develop these habits,one needs to first acknowledge the fact that they needto improve communication skills from time to time.37 The only constant()in lifeis change.The more one accepts one's strengths and works towards dealing with theirshortcomings,the better will be their interactions and the more their social popularity.38 Well,the answer is simple.One can find plenty of literature on this.There arealso experts,who conduct discussion based in communication skills of men and women.Infact,a large number of companies are bringing in trainers to regularly hold sessions on thesubject.This will help their work force maintain better interpersonal work relations.Today,effective communication skills have become a critical factor even whilerecruiting employees.39 They believe that some skills can be improved on the job;butthe ability to communicate well is important,as every employee becomes the representingface of the company.There are trainers,who specialize in certain programs on the subject.40Meanwhile,they also help trainees look into the problems in the way of being able toconvey message effectively.nommovoo riwA.Especially in the area of doing researches.o oT6 on m anomgolovob brs floiss2oB.How to improve communication skills?5003d0021igns116n10150可英语试卷第8页（共12页）
三要点梳理漫画图解基础强化紧扣教材。易错点拨·化学用语。归纳精炼特别提醒·日积月累。重点标注。知识拓展。滚动过关本书随《学练优》配套使用，不单独销售
M:I have a bit of problem,actually.My car isn't working at the moment.I'm thinking of getting a taxi to thestation,and then getting on a train.W:I'll give you a lift to the station.Don't worry.M:OK.Then I'll get a taxi home.Thanks a lot.(Text 8)M:Waitress,this menu is in Chinese.Would you mind giving me the English menu?W:Actually,it's in English and French,too,but it's just in smaller print.Look here.M:Thanks.OK,I'd like to order fried fish with tomato sauce and roast lamb.W:Just the two?M:Oh,wait a moment.I also need the vegetable salad for my wife.She likes it.Some French fries and a cup ofyogurt for my daughter.W:Anything else?M:And also French onion soup.It is my father's favorite.That's enough.W:OK,I've written them down.We'll serve the dishes as soon as possible.M:Oh,my family haven't got here yet,so could you please serve the food in half an hour?W:I see.No problem,sir.(Text 9)W:George.What's happened to your happy smile?M:I was miles away,I'm afraid.Dorothy,I've lost my job.W:You've worked there for six years.M:Yes.Recently the company has been losing money,so they've decided to close it down.W:What are you going to do?Are you going to try and get another job in the music business?M:Well,I thought I might start a recording studio.There are lots of youngsters who can't afford the highprices.I thought I could offer a cut-price recording service.W:Great.Then,as you get more famous,you could increase your charges.M:No,I'd rather encourage young musicians to come and make their first recordings with me and then I thoughtmaybe I could branch out and become an agent.W:Well,if you need someone to help you,let me know.M:OK.(Text 10)W:Attention,please!Parents who want to sign your kids up for the Sandy Creek Youth Basketball Leagueplease listen to these details carefully.Tryouts are just three weeks away.There are four age groups this yearfor boys and three for girls.For boys,please use the blue sheets and for girls,please use the yellow sheets.Once you have completed your sigh-up sheet,please turn it in to the coach.Boys should give your information toCoach Turner or Coach Collins.All girls'sigh-up sheets can go to Coach Dykes over there in the green shirt.Please keep in mind that there are some new rules this season:the three-point line has been moved back half afoot.Also the time for all the games had been increased by two minutes per half.If you and your children haveany further questions,please e-mail me directly.I hope to see all of you soon.And for those of you who want toget even more involved,we always need parent volunteers at both games and practices.Thanks again for yourcontinuing support.·4·【22·zcYK·英语·参考答案一WYB一英语4一QG】
增加：在缺词处加一个漏字符号（入)，并在其下面写出该加的词。删除：把多余的词用斜线（八）划掉。修改：在错的词下画一横线，并在该词下面写出修改后的词。注意：1.每处错误及其修改均仅限一词：2.只允许修改10处，多者（从第11处起)不计分。I ouce ran the first leg of 4x100-metre relay at our annual sports tournament.It was excitedand unforgettable.Standing on the starting line and wait for the starting gun,I could almost hearof my own heart beating.When the gun sounded,I almost remove everything else from mymind.Now I can't remember what I finished my leg of the race.Only when I passed the stick tosecond runner did I hear the crowd cheering but shouting.The whole race was over immediately.The crowd rose to their foot and their cheering became even louder.Our team won the race,andall of them hugged each other tightly for quite a while.I felt real happy.第二节书面表达（满分25分)假定你是李华，正在伦敦交流学，得知当地唐人街将举办中国美食节(Chinese FoodFestival),正在招募志愿者。请你用英文写一封申请信，内容包括：1.写信意图：2.个人优势：3.表达期待。注意：1.词数100左右；2.可适当增加细节，以使行文连贯。Dear Sir/Madam,Yours,Li Hua
第5章物质结构元素周期律学生用人书(2)Z的最高价氧化物的水化物属于②用电子式表示化合物D2W的形成过(填“酸”或“碱”)。程：(3)热稳定性：X的最简单氢化物比Y的最简单氢化物(填“强”或(3)下列事实能说明W元素的非金属性比“弱”)。硫元素的非金属性强的是(填(4)Z在Y2中燃烧生成化合物，1mol该化标号)。合物与水反应时转移电子数为a.W单质与HzS溶液反应，溶液变mol。浑浊(5)Y、M两元素之间形成的化合物，常用b.在氧化还原反应中，1molW单质比作水的消毒剂的是(填1molS得电子多分子式)。c.W和S两元素的简单氢化物受热分12.A、X、W、D、E为短周期元素，且原子序数解，前者的分解温度高依次增大。A、D同主族，X、W同周期，X(4)实验室制备A和X形成的气态化合物形成的气态氢化物可使湿润的红色石蕊试的化学方程式为纸变蓝，A、W能形成两种液态化合物A2W(5)经测定A2W2为二元弱酸，其酸性比碳和A2W2,E元素的周期序数与主族序数酸的还要弱，请写出其第一步电离的电相等。离方程式：(1)E元素在周期表中的位置为(6)废印刷电路板上含有铜，以往的回收方。W的原子结构示意图为法是将其灼烧使铜转化为氧化铜，再用硫酸溶解。现在改用A2W2和稀硫酸(2)①A、X两种元素能形成含18电子的分浸泡废印刷电路板既能达到上述目的，子，请写出该分子的电子式：又保护了环境，试写出反应的离子方程式：429
第二节(共5小题；每小题Lake Baikal((贝加尔a)湖ishebiest body of fateroh.I's about阅读下面短文，从短文后6kmdepth and isso the deepest.Several nsm home项为多余选项。cuding theors only of fesater seal Thereareember ofBka.But the akesrirhow theydoHave you ever wishedwell has been a puzze.A study conducted by Yuuki Watanabe of the Nationalschool?For 700,000 AmerInstitute of Polar Research,in Tokyo,suggests a possible answer.learning has different namMost seals eat fish.And Baikal seals do have needle-like teeth.But in 1982what it is called,this idearesearchers noted that they had some specialized comb-like teeth behind the needlelike ones.At the time,nobody knew what they were for.But Dr.Watanabe supposedinformation on a computerkid spending the day playinthat they might be an adaptation for feeding on other tiny creatures living in the lake.0216Seals arrived in Baikal two million years ago,from the Arctic Ocean.So dida book.Where online eduonline learning simply measome much smaller sea creatures,.known as amphipods(片脚类动物).They havediversified into more than 340 native species.Sea creatures the size of seals would37 Flexibility is tnormally see amphipods to be too small to hunt.But Dr.Watanabe wondered ifand whenever they desire.Baikal seals'comb-like teeth might have evolved to enable the seals to hunt these tinyhas Internet access.Additicreatures to make them useful prey-just as some whales collect extremely smalltheir own pace.所有shellfish using comb-like structures.He and his colleagues therefore attachedAnother advantage owaterproof video cameras to a few seals to monitor what they were getting up to.online schools teach the saScenes from the cameras showed that the seals were indeed pursuing the groups38However,traditioof amphipods at night.Dr.Watanabe estimated that each seal caught an average ofif there are not enough st57 amphipods per dive and thus thousands of them a day.The needle-like teeth areOnline schools also hnot useless,for the seals do hunt fish as well.They compete with those fish for theexample,many online sclamphipods,thus perhaps maintaining themselves in larger numbers.in online classes can watc32.Which aspect of Baikal seals remains unknown?f516329191290bs7W,88other students.Some onlA.Why they live in Lake Baikal./97s1o1ds78bs2i1.△talk with the teacher dirB.How they got into Lake Baikal.195d55131g0519Dmi69打8Computer technologC.When they reached Lake Baikal.omom nortgnone glon vemfriends,listening to musD.How they grow well in Lake Baikal.euorznooni fi vwlJeither have had their ow33.What does the underlined word "they"in paragraph 2 refer to?It looks like online schoA.Researchers.B.Comb-like teeth.16-12.AC.Baikal seals.D.Needle-like teeth.learning is right for you34.Why did researchers attach video cameras to the seals?A.Almost every part oA.To take control of their behaviour patterns.B.Online schools offerB.To record how they coexist with amphipods.C.For some studentsC.To confirm if they live on small water creatures.oniauinoD.Aschools may betterD.To find the similarities between seals and whales.uls,○D.They attend school35.What message is conveyed in the last paragraph?E.Frankly speaking,tA.There is a sharply growing trend towards Baikal seals.F.Other online schooB.Baikal seals prefer hunting amphipods at night.hobbies.C.Needle-like teeth are of litle use to Baikal seals.G.Some online schoD.Baikal seals feed on fish besides amphipods.science,French,o英语试题（附中版）第6页（共10页）
35.What's the best title of the text?A.The Future of Sports ClothesB.Portable Accurate EKG Monitoring DeviceC.The Study of Carbon Nanotube FiberD.Measuring Heart Rate Through a Smart Shirt第二节（共5小题；每小题2.5分，满分12.5分）阅读下面短文，从短文后的选项中选出可以填入空白处的最佳选项。选项中有两项为多余选项。A pile of homework can seem frightening,but it can be done if you make a plan.Here aresome tips to help you.OCreate a checklist of the tasks you have.Before diving in,make a list of all the thingsyou need to do for your homework.36 The satisfaction of checking things off will keepyou happy to continue.OSolve the hardest homework first.Your first thought might be to put off the mostdifficult homework.If you get the hard stuff out of the way when you're most alert,however,it will be easier to get through the rest of the pile.37OAsk for help if you get stuck.If you come to a part of your homework that you don'tknow how to do,ask a family member to help you.38 With a little help,you can quicklymove on to the next thing.OMake a homework schedule.39 If you set a schedule,then you'll be prepared andknow exactly what to do.This will also keep you from feeling guilty about putting homeworkoff.O 40 If everyone in your group is serious about getting homework done,this can begreat.You can help each other out with assignments,and quiz each other to prepare forexams.A.Establish a study group.B.Take a break now and then.C.That way,you won't get discouraged.D.As you complete each task,cross it off your list.E.Try to do your homework at the same time each day.F.Write down all the reasons why you really need to do your homework.G.Make a plan to finish your work bit by bit,saving the easiest tasks for last.第三部分语言运用（共两节，满分30分）第一节（共15小题；每小题1分，满分15分）阅读下面短文，从每题所给的A、B、C、D四个选项中选出可以填入空白处的最佳选项。A student who was preparing to graduate from school sent out invitations to her family inthe hope they would be able to attend on the day.It wasn't until a 41 dropped back in reply that she 42 she had sent one to thewrong address and the message inside is restoring people's 43 in humanity.The card politely informed her that her 44 no longer live at the address,and the newoccupant(居住者)took the time to45 the student on her achievements-一even enclosing$20 inside as a 46.The stranger's heart-warming act was posted on Reddit,where the receiver said,"I47 sent a graduation invitation to my extended family's old address.I received thistouching card(and$20!)48！”It 49,"Regretfully I must inform you that your relatives are not located at thisaddress.I bought this house in September and am not 50 with former owners.Iunknowingly opened the envelope 51 to them by mistake and am returning the invitationto you.That being said,I offer my congratulations!I don't 52 you,but I am proud of【高三英语第6页（共8页）】23206C
A.1Q plays a role in how successful we become.IQ is a measure of a person's reasoning ability.C.Every student can learn,no matter how intelligent.D.Intelligence helps,but so does interest and patience.E.It's tempting for people to read a lot into someone's IQ score.F.In a word,intelligence matters,but not as much as you might think.Many colleges and universities also use exams similar to IQ tests to seleet students.第三部分语言运用（共两节，满分30分）第一节（共15小题；每小题1分，满分15分）阅读下面短文，从每题所给的A、B,C,D四个选项中选出可以填入空白处的最佳选项。One day,I came cross an old lady who looked worried on my way back home from run-ning a special assignment.She stopped me on the sidewalk,41 asking for directions.Igave her the right directions,42 the way she needed to go.But she looked 43 andstarted to tear up,like she had been lost for a while and wasn't 44 with the area.And thefact was like that.It was dark and cold,so I offered to walk with her,45 her it was only a 5-minutewalk.I saw her 46 to walk and keep up the pace,so I 47 down and carried her bagsfor her.I 48 with her during the whole time,getting to know her.I found out she lived out-side of the country and came here temporarily to 49 a sick family member.From what shesaid,I found she was incredibly 50 and kind.When we got to her 51,she cried,gave me a big hug and showed me great 52for helping her.With a smile on my face,I let her know I was 53 she was safe.Mean-while,I 54myself being lost in an unfamiliar place.And I hoped I'd receive similar55 in that situation.A.anxiouslyB.casuallyC.unexpectedlyD.temporarilyA.trackingB.exploringC.pointingD.quoting3A.guiltyB.upsetC.ashamedD.amazedA.familiarB.boredC.disappointedD.satisfiedA.callingB.convincingC.recognizingD.comforting6.A.refuseB.pretendC.hesitateD.struggle7.A.settledB.castC.slowedD.calmed8.A.competedB.chattedC.comparedD.conflictedA.take care ofB.take control ofC.take advantage ofD.take possession ofA.meanB.professionalC.creativeD.sweetA.academyB.officeC.positionD.grocerygratitudeB.impressionC.progressD.interestscaryB.delightedC.embarrassedD.shocked【高三英语第8页（共10页）】·23-288C
液中c(OH)=10-3mol·L1,根据二者反应关系可知：设H2SO4溶液的物质的量浓度为cmol·L1,体积为10V-103V酸=103，解得V酸：V=9:2,A错误；VL,则氢氧化钠溶液的体积为2VL,混合所得溶液的V诚十V酸pH=11的氨水中，c(OH)=c(NHt)=10-3mol·pH=3,即c(H*)=2cV-10-3X2y3Vmol·L1=L1,pH=1的盐酸中，c(H+)=10-1mol·L1,二者等10-3mol·L-1,解得c=2.5×10-3,则H2S04溶液与体积混合后（不考虑混合溶液体积的变化）刚好完全反NaOH溶液物质的量浓度之比应为5：2，B符合题意。应，则c(碱)=c(酸)=10-1mol·L1,故原氨水中NH时7.B解析：氨水稀释后氢氧根离子浓度减小，溶液的pH占N元素总量的10mol·L、7101m0l.元X100%=1%,B正确；减小，将pH=a的氨水稀释10倍后，稀释后的溶液中氢碱溶液中OH大量存在，25℃时pH=8的Ba(OH)2溶氧根离子浓度大于原来的品，溶液的pH=6,则6>2一1，液中，c(OH)=l0-6mol·L-1,pH=10的Na0H溶液A错误；l0mLpH=a的硫酸溶液c(H+)=l0amol·中c(OH)=10-4mol·L-1,二者等体积混合后混合溶液中c(OH)=10-6+10L1,100mLpH=b的Na0H溶液c(OH）=1010-8 mol-mol·L-1,则其中c(Ht)=2·L1=10-14mol·L-1,两溶液混合后，溶液呈中性，则c(0FH)100+10mol·L1=,2x10-410-1410-1410mL×10amol·L1=100mL×10-14mol·L-1,则10-6+104mol·Q十b=13,B正确；同pH、同体积的三种酸溶液分别与少2量且质量相同的Z片反应，反应的均速率与c(H)有L1,C错误；某温度下Km=1×1013,溶液中由水电离出关，由题可知醋酸溶液在整个反应过程中c(H+)更大，则的c(H+)=1×1011mol·L1<√10-mol·L-1,说明反应的均速率为b>a=c,则反应所需时间有：b
秘密★启用前【考试时间：2月7日8：00~10：00】9.What does the woman say about the math course she has already taken?A.She found it very easy2023年重庆一中高2023届2月月考B.She had a hard time keeping up.C.She wasn't satisfied with her grade英语试题卷听第8段材料，回答第10至12题。10.Where does the woman plan to go?注意事项：A.To Mary White's.B.Up north.C.Nowhere.11.Who do you think Mary White is?1.答卷前，考生务必将自己的姓名、准考证号码填写在答题卡上。A.An experienced doctor.B.Their friend.C.Bob's sister.2.作答时，务必将答案写在答题卡上。写在本试卷及草稿纸上无效。12.How many people will go?3.考试结束后，将答题卡交回。A.Two.B.ThreeC.Four.听第9段材料，回答第13至16题。第一部分听力（共两节，满分20分）13.What are the two speakers doing?第一节（共5小题；每小题1分，满分5分）》A.Looking for a gift for the woman's mother.听下面5段对话。每段对话后有一个小题，从题中所给的A、B、C二个选项中选出最佳选项，并标在试B.Window-shopping without purpose.卷的相应位置。听完每段对话后，你都有10秒钟的时间来回答有关小题和阅读下一小题。每段对话仅读一遍。C.Selecting a gift for the man's mother.1.Why didn't the woman make a cake?14.Why is it difficult for the woman to solve the problem?A.She hurt her handsB.She was very busy.C.She disliked cakesA.Because her mother is hard to please2.What is the man used to?B.Because her mother has almost everything.A.Wearing no hat.B.Being done harm to.C.Catching a cold.C.Because there are too many things to choose from.3.Where will Mary probably go tonight?15.Which of the following does the man suggest buying?A.To her hometown.B.To Tom's home.C.To the concert.A.Chinese tea.B.Grape wine.C.Wine glasses.4.Who is probably Hank?16.What do they decide to buy as a gift at last?A.The woman's boss.B.The woman's brother.C.The woman's classmate.A.A teapot.B.A frying pan.C.A pair of glasses5.When is the man checking in?听第10段材料，回答第17至20题。A.On Tuesday.B.On Thursday.C.On Friday.17.What did the writer do one day?第二节（共15小题；每小题1分，满分15分）A.He paid a visit to his friendB.He went to telephone his old friend.听下面5段对话或独白。每段对话或独白后有几个小题，从题中所给的A、B、C三个选项中选出最作选C.He had lunch with his friend项，并标在试卷的相应位置。听每段对话或独白前，你将有时间阅读各个小题，每小题5秒钟；听完后，各小18.Which of the following is true according to this story?题将给出5秒钟的作答时间。每段对话或独白读两遍。A.The writer found it easy to park his car.听第6段材料，回答第6、7题。B.The writer was 20 minutes late for the visit6.What does the woman want to do?C.It was difficult for the writer to find a parking place.A.To buy an MP4.B.To repair her MP4.C.To replace her MP4.19.How did he look for his car?7.What is the man?A.By asking his friend for help.A.A repairman.B.A sales clerk.C.A manager.B.By asking a policeman for help.听第7段材料，回答第8、9题C.By examining every car in the street.8.Why does the woman talk to Professor Smith?20.What can we know from the passage?A.To take an advanced course.A.Driving in the city is a pleasureB.To ask for some advice.B.Traffic in the city is a headache.C.To borrow some booksC.Driving is better than walking.英语·第1页（共8页）英语·第2页（共8页）
考点化学反应速率·考点导航班级：姓名：化学反应速率是化学基本理论的重要组成部分，是高考的热点，但是难度不算太大，主要理解化学反应速率的概念与表达式，理解影响反应速率的因素，从而初步了解调控反应快慢的条件。运用化学视角解释生活中的一些反应速率问题，掌握化学反应速率的简单计算。《必备知识·考点巧练》A.催化反应①是吸热反应，催化反应②是放热知识点一化学反应速率的计算反应1.一定温度下，在2L的密闭容器中，X、Y、Z三种B.E1是催化反应①对应的正反应活化能气体的量随时间变化的曲线如图所示，下列描述C.温度升高，总反应的正反应速率的增加幅度大正确的是(于逆反应速率的增加幅度D.(E2十△H)是催化反应②对应的逆反应活1.58化能交作1.20业时，1.00代关键能力·素养整合》4.一定温度下，向2L恒容密闭容器中充入0.410.210.4 mol NH3和0.5molO2发生反应4NH3(g)沿虚线剪10'时间s+502(g)=4NO(g)+6H20(g)。2min后，A.反应开始到10s时，用Z表示的反应速率为NO的浓度为0.06mol·L-1。下列有关说法错0.158mol。L-1。s-1误的是()B.反应开始到10s时，X的物质的量浓度减少A.0~2min内，02的物质的量减少了0.15mol了0.79mol。L-1B.2min末，NH3的浓度为0.14mol·L-1C.反应开始到10s时，Y的衡转化率为79.0%C.0~2min内，生成水的质量为3.24gD.反应的化学方程式为X(g)+Y(g)—2Z(g)D.2min末，用O2表示的反应速率为知识点二化学反应速率大小比较0.024mol。L-1·min-2.对于可逆反应A(g)十2B(s)一2C(g)+5.将等物质的量的A、B混合于2L的密闭容器中3D(g),在不同条件下的化学反应速率如下，其发生反应3A(g)+B(g)=xC(g)十D(g)。经中表示的反应速率最快的是4min后，测得D的浓度为0.4mol·L-1,C的A.v(A)=1.5mol·L-1·min均反应速率为0.1mol·L-1。min1,c(A):B.v(B)=1.2mol。L-1·s-1c(B)=3:5,下列说法错误的是()C.o(C)=0.2mol·L-1·s1A.x的值是1D.v(D)=0.4mol。L-1·min1B.4min末，B的转化率约为16.7%知识点三影响化学反应速率的因素C.起始时A的浓度为4.8mol。L-13.臭氧层中O3分解过程如图所示，下列说法错误D.4min内，v(B)=0.1mol。L-1。min-1的是()》6.将1molX和3molY在2L的恒容密闭容器中总反应：混合，一定条件下发生反应X(s)+3Y(g)03+0→2022Z(g),1l0min时测得Z的浓度为0.2mol·L1催化反应：下列说法正确的是()反应物①03+Cl—>02+C1003+0②Cl0+0→Cl+02A.l0min内，X的均反应速率为0.01mol·L-1。min-1△H生成物02+02B.10min时，Y的转化率为30%C.反应时，向容器中通入He,容器内压强增大，反应过程但反应速率加快臭氧分解过程示意图D.改变温度对该反应的化学反应速率有影响高你既然认准一条道路，何少去打听要走多久化学61家
姓名准考证号(在此卷上答题无效】C.To buy some gifts for his family.鹅密★启用前What does Judy often do at the railway station?A.Read books.C.Look around the shops.2023全国名校高考分科综合卷B.Call some friends.10.What are the speakers mainly talking about?英语试题（五）A.What to do next year.B.Wbere to go for vacations.本试卷共8页。全卷满分150分，考试时间120分钟C How to pass the waiting time注意事项：听第8段材料，回答第11~13题1答参的，考生务必将自已的姓名准考证号填写在答题卡上11.Why does Bill look troubled?2回容选择题时，选出每小题答案后，用铅笔把答题卡对应题目的答案涂烈。如需改动，用橡A.He is short of money.皮擦干净后，再选涂其它答案标号，回答非选择题时，将答案写在答题卡上，写在本试卷上无效。B.He has made a big mistake.3,考试结束后，将本试题和答题卡一并交回。C.He is facing a tough choice.第一部分听力（共两节，满分30分）12.What is Bill now?做题时，先将容案标在试卷上。录音内容结束后，你将有两分钟的时间将试卷上的答案转涂A.A college student.B.An army officer.C.A computer engineer.到答题卡上。13.What does the woman seem to suggest Bill do?A.Learn to repair cars.B.Decline the job offer.C.Ask his uncle for advice.第一节（共5小题：每小题1.5分，满分1.5分）听下面5段对话，每段对话后有一个小题，从题中所给的A,B.C三个选项中选出最佳选项，门听第9段材料，回答第14~16题。并标在试卷的相应位置。所完每段对话后，你都有10秒钟的时间来同答有关小题和阅读下一小14.What is the woman recommending o the man?A.A writer.B A club.⊙A course.题。每段对话仅读一遍。1.What will the speakers do tonight?15.What is the woman reading now?A.The Beautiful Mind.B/The Great Gatsby,C.The Kite RunnerA.Visit Mary.B/Go out of townC.Host a dinner.16.How much time does the man have to read the book?2.How does the woman go to work this week?A.Two weeks.B.Three weeks.C.Four weeks.A.By car.B.By bike.C.On foot.听第10段材料，回答第17~20题。3.What time does Dave's meeting start?1.Whayis the ypeaker doing?A.At8:30.B.At9:00C.At10:00A.Reporting a study B.Chairing a meeting.C.Teaching a classWhat is Helen going to do?A18.What should you pay most aftention to when taking notes?A.Buy some books.B.Study in the library.C.Attend a history class./△A.Listening.B.Reading.C.Writing9.What is the woman's feeling now?19.What is an advantage of using symbols in note-taking?DA.Relief.B.Regret.C.EmbarrassmentA.It keeps information secret.第二节（共15小题：每小题1.5分，满分22.5分）B.It leaves space for future use.听下面5段对话成独白。每段对话或独白后有几个小题，从题中所给的A,B,C三个选项中C.It makes key words noticeable选出最佳选项，并标在试卷的相应位置。听每段对话或独白前，你将有时间阅读各个小题，每小题20.What will the speaker do next?5秒钟，听完后，各小题将给出5秒钟的作答时间。每段对话或独白读两遍。A Ask a few questions.B.Show some notes.C.Make a summary.所第6段材料，回答第6、7题第二部分阅读（共两节，满分50分）5.What is Tom busy doing?第一节（共15小题：每小题2.5分，满分37.5分）A.Raising money.B.Writing a lab report.C.Giving classes to children.阅读下列短文，从每题所给的四个选项(A,B.C和D)中，选出最佳选项。A7.Who might be able to help Tom this week?A.Mike.B.CathyC.Jane.All dog c beeit from training throughout their lives But where to begin the process?听第？段材料，回答第8~1心题Thuswe have conued ome experts where to start.Here'swhat they say8.Why is Jack leaving early?Identify your training goalsA.To avoid getting stuck in traffieThere levels of dogrtraining o baB.To enjoy the scenery on the wayuchtechng your dogthe field ofog【2023金国名校高考分科综合卷·英语试题（五）第1页（共8页D】【2023全国名校高考分科棕合卷·英语试题（五）第2（共8页】
第二节（共10小题；每小题1.5分，满分15分)【文章大意】本文是一篇说明文。文章主要介绍了中国传统服装一汉服亮相威尼斯狂欢节，说明了中外文化交流的不断加深。61.traditionally【解析】考查副词。修饰动词worn应该用副词作状语，故填traditionally。62.participated【解析】考查动词时态。根据时间状语on Feb..17,2023判断应该填动词过去式。63.dynasties【解析】考查名词。该空表示“四个朝代”，故填名词复数。64.whom【解析】考查定语从句。分析结构可知，此处是非限制性定语从句且从句中缺少主语，因先行词是people,故填whom。65.closer【解析】考查形容词的比较级。get close to是固定短语，因前面有even修饰，故填比较级closer。66.majoring【解析】考查非谓语动词。went是句子的谓语，判断设空处应该用非谓语形式作伴随状语。67.to know【解析】考查非谓语动词。短语would like后应该用不定式作宾语，故填to know。68.a【解析】考查冠词。此处是名词短语作guzheng的同位语，泛指“一种中国传统乐器”，故填a。69.as【解析】考查介词。固定搭配consider.…as意为“认为…是”。70.have been carried【解析】考查时态和语态。根据句意以及时间状语since then判断题空处应该用现在完成时的被动语态，又因主语是activities,故填have been carried。第四部分写作（共两节，满分35分）第一节短文改错（共10小题；每小题1分，满分10分）I love playing football.Insteadjust a year ago I showed no interest in them at all.WhatHowever/Neverthelesschanged my attitude?It was the article introducing Leo Messi.Before reading this article,I only knew about hisanperfectly skills.But later I also learned about his honest,generosity and friendliness,make me one of his faithfulperfecthonestymakingfollowers.I began to watch matches and played football with my classmates.Then,I joined in the school footballplayteam.Though my skills are not good enough for me A compete in the big games,I am making progress day bytoday.But at the same time,I am becoming more and more healthy and confident.And第二节书面表达（满分25分）One possible version:Dear Daniel,I'm glad to hear from you knowing that you have a chance to go on an overseas study tour.It is really a goodopportunity to learn about the world through travelling.First of all,when travelling abroad,you can learn a lot of different things that you have never experienced,which can expand your horizons and gain global perspectives.Besides,travelling with others requires you to dealwith others in a group,which can help develop your cooperative spirit.Additionally,it can develop your problem-solving ability when you meet with difficulties.In a word,I hope you can join in and benefit from it.Best wishesIYours,Li Hua作文评分标准1.本题总分为25分，按5个档次给分。英语参考答案-4
选择题A.500s内NO的分解速率为5.92×10-3mol·L1·s答题区B.T温度下该反应衡时N2O,的转化率为25%C.T时，4NO,(g)+O,(g)一2NO(g)的衡常数为125D.达到衡后，其他条件不变，将容器的体积压缩到原来的)，则c(N,O)<5.00mol·L-1第Ⅱ卷（非选择题共58分)二、非选择题（本题包括4小题，共58分）15.(14分)为探讨浓度对化学衡的影响，某同学对可逆反应2Fe3+(ag)十2I (aq)-2Fe2+(aq)+I2 (aq)△H<0按下图所示步骤进行了一系列实验。3 mL 0.01 mol.L-KI溶液实验I3 mL 0.005 mol-L-棕黄色溶液Fe2(S04)3溶液(pH约为1)分成三等份数滴mL 1 mol.L-1 mL H2O实验Ⅱ0.01mol.L1FeS0a溶液AgNO3溶液ⅱ封已知：0.005mol·L1的Fe2(SO4)3溶液接近无色。(1)实验中要待实验I溶液颜色不再改变时，才能进行实验Ⅱ，目的是(2)实验Ⅱ中，ⅰ的现象是，的颜色变化表明衡(填“正向”或“逆向”)移动，用化学衡移动原理解释原因：(3)实验Ⅱ中，是ⅱ的对比实验，目的是排除ⅱ中造成的影响。(4)实验Ⅱ中，ⅱ的现象是线,即能证明增大生成物浓度使化学衡逆向移动。(5)除了上图中的方法外，若要使该可逆反应的化学衡逆向移动，还可以采用的方法有(任写一种)。16.(16分)Cu及其化合物在生产、国防中有重要的应用。纳米级Cu2O既是航母舰艇底部的防腐蚀涂料，也是优良的催化剂。I.(1)CuO的制备：在100℃的Cu(NO)2溶液中加入一定体积的NaOH溶液，搅拌均匀，再逐滴加入肼（八H),产生红色沉淀，抽滤、洗涤、干燥，得到Cu2O。已知：①N2H4()+O2(g)—N2(g)+2HOI)△H1=-akJ·mol1·21·【24新教材·DY·化学三)一R一选择性必修1一QGA·N
■口■▣■■3.D细节理解题。根据最后一则广告中的“Book early to get a table.”可知Pizza World接受预定。A项错在“light music”;B项错在“Italian boss'”,从文章中看不出老板是意大利人；C项错在“twelve hours a day”,原文中说“Our bar is open all day”。B主题语境：人与自我【语篇导读】本文属于记叙文。介绍了84岁的Janet Fein不断学的故事。4.B细节理解题。根据第一段“84-year-old Janet Fein received her bachelor's degree”一句可知B项正确5.C细节理解题。根据第一段“had a career as a secretary until she retired at age77”可知Janet Fein最后一份工作是秘书.6.C推理判断题。根据第三段中健康专家所说“continuing with education later in life is oneway to keep fit'”可知继续学对人们的健康有益。7.B推理判断题。根据文章大意“84岁的Janet Fein通过不断努力最终获得学士学位”可以推断她是一个有决心的、激励人心的人。C主题语境：人与自然【语篇导读】本文属于科普类说明文。介绍了人的年龄分为两种：实际年龄和生理年龄。在未来，科学家们可以通过控制人类的生理年龄从而延长人类寿命8.C推理判断题。本题推断作者的写作意图，根据第二段的主要内容可知作者向读者说明了“chronological age”以及“biological age”的定义，因此正确答案为C9.B细节理解题。根据文章第四段“Biological age is what determines our health andultimately our lifespan.”可知，因此正确答案为B。10.B主旨大意题。根据文章主要内容可知主旨大意为研究者们发现人们的年龄分为实际年龄和生理年龄，通过对生理年龄的控制和改变可以在一定程度上降低人们的死亡风险。因此正确答案为B。11.D推理判断题。推断文章出处，根据文章主题可知，因此正确答案为D。D主题语境：人与社会【语篇导读】本文属于议论文。作者通过向读者介绍了ChatGPT广泛的用途以及不足之处，讨论了ChatGPT这一新兴人工智能是否是整个科技的彻底变革的问题l2.C细节理解题.根据文章第二段“It might give some good answers to most of the generalquestions”可知，故答案为C.英语参考答案·第3页（共6页）
20.(14分)有机物F是合成抗肿瘤药物的重要中间体，其合成路线如下：OTBSCIOTBSOTBS试剂a,HOTBS一定条件OH乙醚H,OOHABDA OH已知：i.u为人OMgBrOHR,MgBrHi.乙醚一R2H20RR2R回答下列问题：(1)化合物E中含氧官能团名称为,A→B反应类型为(2)F中所含手性碳原子的数目为,试剂a的结构简式为(3)TBSC1的作用是(4)B→C方程式为(5)A在一定条件下与足量的乙酸发生反应的化学方程式(6)已知碳氧元素可形成类似的环状有机物，请写出1种同时符合下列条件的化合物A的同分异构体的结构简式（不包括立体异构体）①分子中存在六元环：②不与钠反应：③HMR显示只有4种不同化学环境的氢原子化学试卷第8页（共8页）
高三第一轮复周湖卷(2)已知步骤③的氧化产物是SO片，写出该反应的离子方程式：(3)某同学取步骤③所得的溶液于试管中，滴加足量盐酸、BaC2溶液产生白色沉淀，他认为通刻测定产生的白色沉淀的质量即可求出实验所用Na2CS的量，你是否同意他的观,请说明理由：实验2：测定Na2CS溶液的浓度稀硫酸无水CaCl2碱石灰+NazCSCuSONaOH溶液自三溶液溶液AR按如图所示连接好装置，取50mLNa2CS,溶液置于A中，打开仪器d的活塞，滴入足量2.0mol·L-1的稀H2SO4,关闭活塞，已知：Na2CSg十H2SO4一Na2SO,十CS2十H2S个。CS2和H2S均有毒。CS2不溶于水，沸点为46℃，与CO2的某些性质相似，与NaOH反应生成Na2COS和HO。(4)盛放无水CaCl2的仪器名称是,B中发生反应的离子方程式是(5)反应结束后打开止水夹K,再缓慢通人一段时间热N2,其目的是(6)为了计算Na2CS溶液的浓度，对B中混合物进行过滤、洗涤、干燥、称重，得到14.4g固体，则A中Na2CS3溶液的物质的量浓度为。【解题分析】(6)当A中反应完全后，打开止水夹K,再缓慢通入一段时间热N2,然后对B中的混合物进行过滤，洗涤、千、称重，得到14.4gCuS固体，n(CuS)=0.15mol,根据关系式Na2CS~H2SCuS,得n(NaCS)=n(CuS)=0.15mol,c(Na2CS3)=3.0mol·L-1。【答案】(1)弱(2分)(2)5CS￥-+24MnO万+52Ht-5C02+15SO￥+24Mn2++26H2O(3分)(3)不同意(2分)；因为酸性KMnO,溶液中含H2SO4,其中的SO?会引起实验误差(2分)(4)球形千燥管(2分)；Cu2+十H2S=CuS￥+2H+(2分)(5)将装置中残留的H2S、CS2全部排入后续装置中，使其被完全吸收(2分)(6)3.0mol·L-1(3分)18【24·G3ZC(新高考).化学-R-必考-QGA-Y】扫码使用Q夸克扫描王
With your 49,I'd like to use a photo of yourMany of our medicines have come from orwork for the cover of our next issue."阅have been inspired by nature.The extinction语言知“Of course,please,,”Jim said immediately ashe 50 that this could be a chance to help Mom.of plants and animals takes away theHe didn't 51 understand everything the manpotential for new cures and drugs that we理解have yet to discover.D 40said,but there was nothing to lose by trying.Soon Mr Finn returned to interview him.C49.A.orderB.request运C.permissionD.supportA 50.A.realizedB.promisedC.explainedD.confirmedgD51.A.slightly B.hardly C.partly D.fullyA.However,that is not always the caseB.Loss of habitat is by far the biggest cause.It was52 that Jim's artwork had achieved hugeC.Avoid buying products made from endangeredsuccess,and plenty of people ordered clothes withanimals.his art on them.Jim earned money 53D.And that will greatly affect the development ofIt was a proud day for Jim when he entered the知hospital to 54 Mom's medical bill.理medicine.D52.A.discoveredB.concludedE.They can only learn about them in books or onthe Internet.C.predictedD.provedF.This means they are responsible for the运B53.A.at all costsB.as a consequenceC.in a senseD.on all sidesreproduction of plants.G.What that means is that we are at risk of losing用54.A.add upB.figure outD.bring backthese animals completely.C.pay off三第一节完形填空After dinner,,Jim showed his sketch(素描)to语言知Mom.“You have a lot of talent..”Mom held Jim'sHe could never have guessed luck woulddrawing up to41it.“Thanks,Mom,”Jim语言知come in a(n)55 wayreplied and couldn't help but notice how 42 shelooked.Then Mom fell onto the floor and was takenAto the 43.55.A.unexpectedB.creativeC.differentD.impressive运B41.A.unfold B.admire C.checkD.analyse运用A42.A.tiredB.gentleC.excitedD.boredB43.A.bedroomB.hospitalgC.yardD.restaurantg三第二节阅读下面短文，在空白处填入1个适Jim's heart 44 when he saw the pitiful当的单词或括号内单词的正确形式。collection of coins and bills in the money box."Er语言知..this won't be 45 I'm afraid,"the doctor saidJavan rhinos are one of the five 56.endangered(endanger)rhino species,with only around 60when Jim presented the box to himindividuals living only in Ujung Kulon NationalIt was getting 46,but Jim wasn't prepared togo home yet.知Park in Java,Indonesia.They once57.lived (live)throughout northeast IndiaC44.A.changedB.stopped识and Southeast Asia.运C.achedD.softenedThe population in Ujung Kulon National ParkA45.A.enoughB.accuraterepresents the only hope for the survival of a speciesC.availableD.practical用that is on the edge of 58.extinction (extinct).If weeD46.A.cloudy B.sunny C.brightD.darklose the population in Java,the entire species willQdisappear.三47,he sat down beneath a streetlight and drewJavan rhinos are at risk of dying out duelines on the ground with a stick to form his59.to habitat destruction,diseases,illegal语言知mother's smiling face.hunting and potential inbreeding(近亲繁殖).LowWhen he'd finished,Jim found a(n)48 mangenetic diversity and inbreeding could make itstanding behind him.He gave Jim a friendly smile言and said,"I'm the editor-in-chief of a local artdifficult for the long-term survival of the species.The coastal Ujung Kulon National Park is easymagazine,and I love what you've done here.识60.to be destroved(destroy)by tsunamis(海啸)，运用C47.A.OtherwiseB.Moreover运and a major eruption of the nearby Anak KrakatauC.InsteadD.Thereforevolcano(火山)could easily wipe61.outB48.A.seriousB.strangemost life in the protected area.62.RisingC.familiarD.interesting(rise)sea levels also threaten the park.6
RCoWlo)o[UR闭]cdRh)R+o刚成松（师7.达得卫浓魔被号二元碱R(OH2在水溶液中含R微粒有RO2ROH、R2+。當温下，水溶液的pH(溶液体积保持不变)，含R微粒的物质的量分数(Q魔pH的变化情况如项T题图调节0.1molL[R(OH)C公项是符所示。已知a点坐标为(4.5,0.5)，c点坐标为(9.5,0.5)。下列说法循误为是A.R(OH2对应的变化曲线为B.R(OH田2的二级电离常数的数量级为1010C.b点溶液pH约为6D.调节溶液pH前，[R(OH]CI水溶液中R2+与R(OH2近似相等斗加0二非选择题（包括必考题和选考题两部分。第810题为必考题，11~12题为选考题，考生根据要求做答。)每个试题考生都必须做答。第(一)必考题(3题，共43分)p8.(14分)利用糠醛的歧化反应可制备糠醇和糠酸，根据所给信息，回答下列问题，叫实验原理：NaOHCHOCH2OHCOONa糠醛糠醇该药物的说+HCINaClCOONaCOOH(白糠酸实验步骤：月子→有机相操作产品120 nLNaOH溶液乙醚7.68g糠醛8-12℃操作1水相操作粗产品提线产品2pH=3恒温加热器(注：a中盛放NaOH溶液；b中盛放糠醛)实验数据：物质糠醛糠醇糠酸乙醚熔点/C)-36.5-29133-116.3沸点/(C)161.717023134.5→Y+n发密度/(g/cm)1.21.11.30.7比值等手溶解性可溶于水，易溶于乙醚易溶于热微溶(1)仪器a的容积应为mL(填标号)。A.25mLB.50mLC.100mL天·D.250mL(2)仪器b的名称为滴加液体常将上口玻璃塞取下，套目的是(3)将操作1补充完整：将反应后溶液装入分液漏斗中，加入乙醚，塞好塞子，将分液漏斗放在铁圈上静置分层，打开上口塞子，再打开活塞，从下端放出水列说法中相，从上端倒出有机相。(4)超过170℃，糠醇的结构易遭到破坏，据此推断操作2一“（填操作名称）。(5)操作3为蒸发浓缩、趁热过滤、、抽滤，再用冷水洗涤，用冷水洗涤的目的是(6)产品1的质量为2.84g,则糠醇的产率为%(小数点后保留1位)。9.(15分)利用铜钴硫化物精矿可削备陶瓷制品的上色染料钴蓝(C0O)和铜，其工艺流程如下图所示，回答下列问题：纯碱→有机相→反萃取→0S0溶液电餐0精郴粉+佛整中→取-冰格→一草Q孕00at fe3=cos滤渣8oaG6加+e=单科模拟02化学09千.c904
(1)用滴定管取待测盐酸溶液25.00mL于锥形瓶中，滴加2滴酚酞作指示剂。若盛装NaOH标准溶液的碱式滴定管中液面位置如图所示，则读数为mL(2)滴定过程中，眼睛应始终注视(3)滴定终点的判断依据是Ⅱ.数据记录实验编号盐酸待测体积ml消耗NaOH标准液体积Vml125.0020.80225.0020.00325.0019.95425.0020.05.数据处理(4)计算该盐酸溶液的浓度c(HC)=mol/L(精确到小数点后4位)。V.误差分析(5)以下操作会导致待测盐酸浓度测定结果偏高的是（填字母)。A.装待测液前，锥形瓶中有少量蒸馏水B.滴定过程中锥形瓶内壁有NaOH标准溶液附着，滴定终点时仍未流下C.滴定前滴定管尖嘴部分有气泡，滴定后气泡消失D.观察读数时，滴定前仰视，滴定后俯视V.拓展(6)常温下，若用0.1000mol.L'NaOH溶液分别滴定20.00mL等浓度的盐酸和醋酸溶液，得到两条滴定曲线，如图所示：PHPHEV(NaOH)/mLV(NaOH)/mL图1图2请回答：①图2表示NaOH溶液滴定(填“盐酸”或“醋酸”)的滴定曲线②达到B、D状态时，反应消耗的NaOH溶液的体积ab(填“>”“<”或“=”)。28.(16分)I.N20和C0是常见的环境污染气体。(I)对于反应NO(g)十CO(g)一CO2(g)十N(g)来说，“Fe+”可作为此反应的催化剂。其总反应分两步进行：第一步为Fe+N2O=FeO+N2:则第二步为(写方程式)。己知第二步反应几乎不影响总反应达到衡所用的时间，由此推知，第一步反应的活化能(填“大于”“小于”或“等于”)第二步反应的活化能。高二化学学科试题第6页共8页
